Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ2 O 1,N,N′,O 1′}cobalt(III) monohydrate
نویسنده
چکیده
The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octa-hedral cobalt(III) complex with a 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent mol-ecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O-H⋯O hydrogen bonds may help to stabilize the crystal packing.
منابع مشابه
Diaqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ2 O,N,N′,O′}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate
In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two ...
متن کاملAquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2 O 1,N,N′,O 1′}cobalt(III) dimethylformamide monosolvate
In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetra-dentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl-formamide (DMF) monosolvate. In the crystal, complex mol-ecules are linked via O-H(...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoterbium(III)zinc(II)
In the title heteronuclear Zn(II)-Tb(III) complex (systematic name: {6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-id-yne)]diphenolato-1κ(4)O(6),O(1),O(1'),O(6')}:2κ(4)O(1),N,N',O(1')-μ-nitrato-1:2κ(2)O:O'-dinitrato-1κ(4)O,O'-terbium(III)zinc(II)), [TbZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-enedi...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoholmium(III)zinc(II)
In the title heteronuclear Zn(II)-Ho(III) complex (systematic name: {μ-6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κ(4)O(1),O(1'),O(6),O(6'):2κ(4)O(1),N,N',O(1'))-μ-nitrato-1:2κ(2)O:O'-dinitrato-1κ(4)O,O'-holmium(III)zinc(II)), [HoZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-ened...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoeuropium(III)zinc(II)
In the title heteronuclear Zn(II)-Eu(III) complex [systematic name: {6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ(4)O(1),O(1'),O(6),O(6'):2κ(4)O(1),N,N',O(1')}-μ-nitrato-1:2κ(2)O:O'-dini-trato-1κ(4)O,O'-europium(III)zinc(II)], [EuZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-enedi...
متن کامل